Proton-triggered octopolar NLO chromophores

被引：47

作者：

Asselberghs, Inge

Hennrich, Gunther

Clays, Koen

机构：

[1] Katholieke Univ Leuven, Dept Chem, B-3001 Leverlee, Belgium

[2] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2006年 / 110卷 / 19期

关键词：

D O I：

10.1021/jp061452m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

C-3-symmetric, octopolar 1,3,5-alkynylbenzenes with terminal pyridyl substituents are presented which show an increase up to 17-fold in the second-order NLO activity upon protonation while maintaining their octopolar character, as confirmed by the depolarization ratios measured.

引用

页码：6271 / 6275

页数：5

共 51 条

[1] Switching of molecular second-order polarisability in solution
Asselberghs, I
Clays, K
Persoons, A
Ward, MD
McCleverty, J
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (19) : 2831 - 2839
[2] Reversible switching of molecular second-order nonlinear optical polarizability through proton-transfer
Asselberghs, I
Zhao, Y
Clays, K
Persoons, A
Comito, A
Rubin, Y
[J]. CHEMICAL PHYSICS LETTERS, 2002, 364 (3-4) : 279 - 283
[3] Synthesis and crystal structure of catena-poly[Rh2(OAc)4(C27H15N3)]•2CH2Cl2, a novel Rh(II) organic/inorganic coordination polymer
Chapman, CT
Goforth, AM
Pschirer, NG
Smith, MD
Bunz, UHF
zur Loye, HC
[J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2003, 33 (11) : 885 - 890
[4] CHO BR, 2001, J CHEN MAT, V13, P1483
[5] Alkynyl compounds and nonlinear optics
Cifuentes, MP
Humphrey, MG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (24) : 3968 - 3981
[6] HYPER-RAYLEIGH SCATTERING IN SOLUTION
CLAYS, K
PERSOONS, A
[J]. PHYSICAL REVIEW LETTERS, 1991, 66 (23) : 2980 - 2983
[7] Clays K., 1994, ADV CHEM PHYS, V85, P455
[8] Coe BJ, 1999, CHEM-EUR J, V5, P2464, DOI 10.1002/(SICI)1521-3765(19990903)5:9<2464::AID-CHEM2464>3.0.CO
[9] 2-L
[10] Theoretical analyses of the effects on the linear and quadratic nonlinear optical properties of N-arylation of pyridinium groups in stilbazolium dyes
Coe, BJ
Beljonne, D
Vogel, H
Garín, J
Orduna, J
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (44) : 10052 - 10057

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