Selective catalytic oxidation of benzyl alcohols to benzaldehydes with a dinuclear manganese(IV) complex

被引：118

作者：

Zondervan, C

Hage, R

Feringa, BL

机构：

[1] UNIV GRONINGEN,GRONINGEN CTR CATALYSIS & SYNTH,DEPT ORGAN & MOL INORGAN CHEM,NL-9747 AG GRONINGEN,NETHERLANDS

[2] UNILEVER RES LABS,NL-3130 AC VLAARDINGEN,NETHERLANDS

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 05期

关键词：

D O I：

10.1039/a607779j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dinuclear manganese(IV) catalyst is capable of oxidising benzylic alcohols to benzaldehydes with very high turnovers numbers (up to 1000) and high selectivities (above 99%).

引用

页码：419 / 420

页数：2

共 15 条

[1] [Anonymous], 1986, ORGANIC SYNTHESIS OX
[2] [Anonymous], ADV ORGANIC CHEM
[3] THE CHEMISTRY OF 1,4,7-TRIAZACYCLONONANE AND RELATED TRIDENTATE MACROCYCLIC-COMPOUNDS
CHAUDHURI, P
WIEGHARDT, K
[J]. PROGRESS IN INORGANIC CHEMISTRY, 1987, 35 : 329 - 436
[4] COREY EJ, 1975, TETRAHEDRON LETT, P2647
[5] De Vos D.E., 1996, J CHEM SOC CHEM COMM, P917
[6] Highly selective epoxidation catalysts derived from intrazeolite trimethyltriazacyclononane-manganese complexes
DeVos, DE
Meinershagen, JL
Bein, T
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (19): : 2211 - 2213
[7] PREPARATION AND USE OF TETRA-NORMAL-BUTYLAMMONIUM PER-RUTHENATE (TBAP REAGENT) AND TETRA-NORMAL-PROPYLAMMONIUM PER-RUTHENATE (TPAP REAGENT) AS NEW CATALYTIC OXIDANTS FOR ALCOHOLS
GRIFFITH, WP
LEY, SV
WHITCOMBE, GP
WHITE, AD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) : 1625 - 1627
[8] EFFICIENT MANGANESE CATALYSTS FOR LOW-TEMPERATURE BLEACHING
HAGE, R
IBURG, JE
KERSCHNER, J
KOEK, JH
LEMPERS, ELM
MARTENS, RJ
RACHERLA, US
RUSSELL, SW
SWARTHOFF, T
VANVLIET, MRP
WARNAAR, JB
VANDERWOLF, L
KRIJNEN, B
[J]. NATURE, 1994, 369 (6482) : 637 - 639
[9] ZR-CATALYZED OXIDATION OF ALCOHOLS TO ALDEHYDES IN THE PRESENCE OF TERTIARY BUOOH - HIGH REACTIVITY FOR PRIMARY AND ALLYLIC HYDROXYL FUNCTIONS
KANEDA, K
KAWANISHI, Y
TERANISHI, S
[J]. CHEMISTRY LETTERS, 1984, (09) : 1481 - 1482
[10] TRANSITION-METAL CATALYZED OXIDATION OF ALCOHOLS TO ALDEHYDES AND KETONES BY MEANS OF ME3SIOOSIME3
KANEMOTO, S
OSHIMA, K
MATSUBARA, S
TAKAI, K
NOZAKI, H
[J]. TETRAHEDRON LETTERS, 1983, 24 (21) : 2185 - 2188

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