Tuning the structure and reactivity of the [Cu-2(mu-O)(2)](2+) core: Characterization of a new bis(mu-oxo)dicopper complex stabilized by a sterically hindered dinucleating bis(triazacyclononane) ligand

被引：106

作者：

Mahapatra, S

Young, VG

Kaderli, S

Zuberbuhler, AD

Tolman, WB

机构：

[1] UNIV BASEL,INST ANORGAN CHEM,CH-4056 BASEL,SWITZERLAND

[2] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1997年 / 36卷 / 1-2期

关键词：

copper; enzyme mimetics; N ligands; O-O activation;

D O I：

10.1002/anie.199701301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：130 / 133

页数：4

共 29 条

[1]

[Anonymous], ACTIVE OXYGEN BIOCH

[2] MIXED-VALENCE MANGANESE-(II, III) AND MANGANESE-(III, IV) DINUCLEAR COMPLEXES - PREPARATION, STRUCTURE, MAGNETOCHEMISTRY, AND ELECTRON-SPIN-RESONANCE SPECTRA OF MN2(BIPHEN)2(BIPHENH)(BPY)2 AND MN2O2CL2(OAC)(BPY)2 (BIPHENH2 = 2,2'-BIPHENOL, BPY = 2,2'-BIPYRIDINE) [J].

BASHKIN, JS ;

SCHAKE, AR ;

VINCENT, JB ;

CHANG, HR ;

LI, QY ;

HUFFMAN, JC ;

CHRISTOU, G ;

HENDRICKSON, DN .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (11) :700-702

[3] SYNTHESIS OF A NEW BINUCLEATING LIGAND LH(4) - SYNTHESIS AND X-RAY STRUCTURES OF ANTI-[CO-2(LH(4))(OH2)(2)](NO3)(4).5H2O, ANTI-[NI-2(LH(4))(NCME)(2)](PF6)(4).4H2O, ANTI-[ZN-2(LH(4))(NO3)(2)](NO3)(2) AND SYN-[CU-2(LH(2))](BPH(4))(2) [J].

BLAKE, AJ ;

DONLEVY, TM ;

ENGLAND, PA ;

FALLIS, IA ;

PARSONS, S ;

ROSS, SA ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (17) :1981-1982

[4] [L2MN2(MU-O)2(MU-O2)](CLO4)2 - THE 1ST BINUCLEAR (MU-PEROXO)DIMANGANESE(IV) COMPLEX (L = 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE) - A MODEL FOR THE S4-]S0 TRANSFORMATION IN THE OXYGEN-EVOLVING COMPLEX IN PHOTOSYNTHESIS [J].

BOSSEK, U ;

WEYHERMULLER, T ;

WIEGHARDT, K ;

NUBER, B ;

WEISS, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (17) :6387-6388

[5] Trinuclear intermediate in the copper-mediated reduction of O-2: Four electrons from three coppers [J].

Cole, AP ;

Root, DE ;

Mukherjee, P ;

Solomon, EI ;

Stack, TDP .

SCIENCE, 1996, 273 (5283) :1848-1850

[6] A MONOMERIC SIDE-ON SUPEROXOCOPPER(II) COMPLEX - CU(O-2)(HB(3-TBU-5-IPRPZ)(3)) [J].

FUJISAWA, K ;

TANAKA, M ;

MOROOKA, Y ;

KITAJIMA, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (26) :12079-12080

[7] THE CRYSTAL-STRUCTURE OF [1,2-BIS(1,4,7-TRIAZA-1-CYCLONONYL)ETHANFE]BR3.4H2O - A LOW-SPIN HEXAMINEIRON(III) COMPLEX [J].

GEILENKIRCHEN, A ;

WIEGHARDT, K ;

NUBER, B ;

WEISS, J .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1989, 44 (10) :1333-1335

[8] Reversible cleavage and formation of the dioxygen O-O band within a dicopper complex [J].

Halfen, JA ;

Mahapatra, S ;

Wilkinson, EC ;

Kaderli, S ;

Young, VG ;

Que, L ;

Zuberbuhler, AD ;

Tolman, WB .

SCIENCE, 1996, 271 (5254) :1397-1400

[9]

HALFEN JA, IN PRESS INORG SYNTH

[10] SYNTHESIS AND X-RAY AND NEUTRON STRUCTURES OF ANTI-[L2RH2(H)2(MU-H)2](PF6)2 (L = 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE) AND A RELATED SPECIES CONTAINING A SYN-[RH2(H)2(MU-H)2]2+ CORE - ISOLATION OF [L2FE2(MU-H)3]BPH4 [J].

HANKE, D ;

WIEGHARDT, K ;

NUBER, B ;

LU, RS ;

MCMULLAN, RK ;

KOETZLE, TF ;

BAU, R .

INORGANIC CHEMISTRY, 1993, 32 (20) :4300-4305

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