Separation of bulk hydrogen sulfide hydrogen mixtures by selective surface flow membrane

被引:16
作者
Parrillo, DJ [1 ]
Thaeron, C [1 ]
Sircar, S [1 ]
机构
[1] AIR PROD & CHEM INC,ALLENTOWN,PA 18195
关键词
D O I
10.1002/aic.690430910
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The separation performance of binary hydrogen sulfide-hydrogen mixtures by a nanoporous carbon membrane called selective surface flow (SSF) membrane is described. The membrane selectively permeates H2S from H-2, and a H-2-enriched stream is produced at the feed-gas pressure. A two-stage embodiment of the SSF membrane is described for production of high-purity H-2 with high H-2 recovery from an equimolar H2S-H-2 feed gas. A novel protocol for operation of the two-stage membrane is needed to achieve that separation goal.
引用
收藏
页码:2239 / 2245
页数:7
相关论文
共 13 条
[1]   Multicomponent gas separation by selective surface flow (SSF) and poly-trimethylsilylpropyne (PTMSP) membranes [J].
Anand, M ;
Langsam, M ;
Rao, MB ;
Sircar, S .
JOURNAL OF MEMBRANE SCIENCE, 1997, 123 (01) :17-25
[2]  
Breck D. W., 1973, ZEOLITE MOL SIEVES
[3]  
Golden, 1992, US Pat.,, Patent No. 5104425
[4]  
Hirshfelder J. O., 1954, MOL THEORY GASES LIQ
[5]  
PARANJAPE M, 1997, IN PRESS CAN J CHEM
[6]   Performance and pore characterization of nanoporous carbon membranes for gas separation [J].
Rao, MB ;
Sircar, S .
JOURNAL OF MEMBRANE SCIENCE, 1996, 110 (01) :109-118
[7]   NANOPOROUS CARBON MEMBRANES FOR SEPARATION OF GAS-MIXTURES BY SELECTIVE SURFACE FLOW [J].
RAO, MB ;
SIRCAR, S .
JOURNAL OF MEMBRANE SCIENCE, 1993, 85 (03) :253-264
[8]  
SIRCAR S, 1997, OPERATION SSF MEMBRA
[9]  
SPILLMAN RW, 1989, CHEM ENG PROG, V85, P41
[10]   MOLECULAR MULTIPOLE MOMENTS [J].
STOGRYN, DE ;
STOGRYN, AP .
MOLECULAR PHYSICS, 1966, 11 (04) :371-+