Electroactive nanofibrillated cellulose aerogel composites with tunable structural and electrochemical properties
被引:111
作者:
Carlsson, Daniel O.
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h-index: 0
机构:Uppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, Sweden
Carlsson, Daniel O.
Nystrom, Gustav
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h-index: 0
机构:Uppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, Sweden
Nystrom, Gustav
Zhou, Qi
论文数: 0引用数: 0
h-index: 0
机构:
Royal Inst Technol, Dept Fibre & Polymer Technol, SE-10044 Stockholm, Sweden
Royal Inst Technol, Wallenberg Wood Sci Ctr, SE-10044 Stockholm, SwedenUppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, Sweden
Zhou, Qi
[2
,3
]
Berglund, Lars A.
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h-index: 0
机构:
Royal Inst Technol, Dept Fibre & Polymer Technol, SE-10044 Stockholm, Sweden
Royal Inst Technol, Wallenberg Wood Sci Ctr, SE-10044 Stockholm, SwedenUppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, Sweden
Berglund, Lars A.
[2
,3
]
Nyholm, Leif
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h-index: 0
机构:
Uppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, SwedenUppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, Sweden
Nyholm, Leif
[1
]
Stromme, Maria
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h-index: 0
机构:
Uppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, SwedenUppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, Sweden
Stromme, Maria
[1
]
机构:
[1] Uppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, Sweden
[2] Royal Inst Technol, Dept Fibre & Polymer Technol, SE-10044 Stockholm, Sweden
[3] Royal Inst Technol, Wallenberg Wood Sci Ctr, SE-10044 Stockholm, Sweden
This work presents conductive aerogel composites of nanofibrillated cellulose (NFC) and polypyrrole (PPy) with tunable structural and electrochemical properties. The conductive composites are prepared by chemically polymerizing pyrrole onto TEMPO-oxidized cellulose nanofibers dispersed in water and the various nanostructures are obtained employing different drying methods. Supercritical CO2 drying is shown to generate high porosity aerogel composites with the largest surface area (246 m(2) g(-1)) reported so far for a conducting polymer-paper based material, whereas composites produced by ambient drying attain high density structures with mechanical properties significantly surpassing earlier reported values for cellulose-conducting polymer composites when normalized with respect to the content of reinforcing cellulose (Young's modulus = 0.51 GPa, tensile strength = 10.93 MPa and strain to failure = 2.5%). Electrochemical measurements clearly show that differences in the porosity give rise to dramatic changes in the voltammetric and chronoamperometric behavior of the composites. This indicates that mass transport rate limitations also should be considered, in addition to the presence of a distribution of PPy redox potentials, as an explanation for the shapes of the voltammetric peaks. A specific charge capacity of similar to 220 C g(-1) is obtained for all composites in voltammetric experiments performed at a scan rate of 1 mV s(-1) and this capacity is retained also at scan rates up to 50 mV s(-1) for the high porosity composites. The composites should be applicable as electrodes in structural batteries and as membranes in ion exchange applications requiring exchange membranes of high mechanical integrity or high porosity.
机构:
Sch Mat, Ctr Mat Sci, Manchester M1 7HS, Lancs, England
NW Composites Ctr, Manchester M1 7HS, Lancs, EnglandInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Eichhorn, S. J.
;
Dufresne, A.
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h-index: 0
机构:
Int Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, FranceInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Dufresne, A.
;
Aranguren, M.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Nacl Mar del Plata, Natl Inst Res Sci & Technol Mat INTEMA, Mar Del Plata, Buenos Aires, ArgentinaInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Aranguren, M.
;
Marcovich, N. E.
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h-index: 0
机构:
Univ Nacl Mar del Plata, Natl Inst Res Sci & Technol Mat INTEMA, Mar Del Plata, Buenos Aires, ArgentinaInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Marcovich, N. E.
;
Capadona, J. R.
论文数: 0引用数: 0
h-index: 0
机构:
Louis Stokes Cleveland DVA Med Ctr, Cleveland, OH 44106 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Capadona, J. R.
;
Rowan, S. J.
论文数: 0引用数: 0
h-index: 0
机构:
Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Rowan, S. J.
;
Weder, C.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Fribourg, Adolphe Merkle Inst, CH-1700 Fribourg, SwitzerlandInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Weder, C.
;
Thielemans, W.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Nottingham, Fac Engn, Sch Chem, Nottingham NG7 2RD, England
Univ Nottingham, Fac Engn, Proc & Environm Res Div, Nottingham NG7 2RD, EnglandInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Thielemans, W.
;
Roman, M.
论文数: 0引用数: 0
h-index: 0
机构:
Virginia Tech, Dept Wood Sci & Forest Prod, Blacksburg, VA 24061 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Roman, M.
;
Renneckar, S.
论文数: 0引用数: 0
h-index: 0
机构:
Virginia Tech, Dept Wood Sci & Forest Prod, Blacksburg, VA 24061 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Renneckar, S.
;
Gindl, W.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Nat Resources & Appl Life Sci, Dept Mat Sci & Proc Engn, BOKU Vienna, Vienna, AustriaInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Gindl, W.
;
Veigel, S.
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h-index: 0
机构:
Wood K Plus, Competence Ctr Wood Composites & Wood Chem, Linz, AustriaInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Veigel, S.
;
Keckes, J.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Leoben, Dept Mat Phys, Erich Schmid Inst Mat Sci, Austrian Acad Sci, Leoben, AustriaInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Keckes, J.
;
Yano, H.
论文数: 0引用数: 0
h-index: 0
机构:
Kyoto Univ, Res Inst Sustainable Humanosphere, Kyoto 6110011, JapanInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Yano, H.
;
Abe, K.
论文数: 0引用数: 0
h-index: 0
机构:
Kyoto Univ, Res Inst Sustainable Humanosphere, Kyoto 6110011, JapanInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Abe, K.
;
Nogi, M.
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h-index: 0
机构:
Kyoto Univ, Res Inst Sustainable Humanosphere, Kyoto 6110011, JapanInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Nogi, M.
;
Nakagaito, A. N.
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h-index: 0
机构:
Kyoto Univ, Res Inst Sustainable Humanosphere, Kyoto 6110011, JapanInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Nakagaito, A. N.
;
Mangalam, A.
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h-index: 0
机构:
Virginia Tech, Dept Wood Sci & Forest Prod, Blacksburg, VA 24061 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Mangalam, A.
;
Simonsen, J.
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h-index: 0
机构:
Oregon State Univ, Dept Wood Sci & Engn, Corvallis, OR 97331 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Simonsen, J.
;
Benight, A. S.
论文数: 0引用数: 0
h-index: 0
机构:
Portland State Univ, Dept Chem, Portland, OR 97207 USA
Portland State Univ, Dept Phys, Portland, OR 97207 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Benight, A. S.
;
Bismarck, A.
论文数: 0引用数: 0
h-index: 0
机构:
Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, Polymer & Composite Engn Grp PACE, London SW7 2AZ, EnglandInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Bismarck, A.
;
Berglund, L. A.
论文数: 0引用数: 0
h-index: 0
机构:
KTH, Wallenberg Wood Sci Ctr, Dept Fibre & Polymer Technol, S-10044 Stockholm, SwedenInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Berglund, L. A.
;
Peijs, T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ London, Ctr Mat Res, London E1 4NS, EnglandInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
机构:
Sch Mat, Ctr Mat Sci, Manchester M1 7HS, Lancs, England
NW Composites Ctr, Manchester M1 7HS, Lancs, EnglandInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Eichhorn, S. J.
;
Dufresne, A.
论文数: 0引用数: 0
h-index: 0
机构:
Int Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, FranceInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Dufresne, A.
;
Aranguren, M.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Nacl Mar del Plata, Natl Inst Res Sci & Technol Mat INTEMA, Mar Del Plata, Buenos Aires, ArgentinaInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Aranguren, M.
;
Marcovich, N. E.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Nacl Mar del Plata, Natl Inst Res Sci & Technol Mat INTEMA, Mar Del Plata, Buenos Aires, ArgentinaInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Marcovich, N. E.
;
Capadona, J. R.
论文数: 0引用数: 0
h-index: 0
机构:
Louis Stokes Cleveland DVA Med Ctr, Cleveland, OH 44106 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Capadona, J. R.
;
Rowan, S. J.
论文数: 0引用数: 0
h-index: 0
机构:
Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Rowan, S. J.
;
Weder, C.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Fribourg, Adolphe Merkle Inst, CH-1700 Fribourg, SwitzerlandInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Weder, C.
;
Thielemans, W.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Nottingham, Fac Engn, Sch Chem, Nottingham NG7 2RD, England
Univ Nottingham, Fac Engn, Proc & Environm Res Div, Nottingham NG7 2RD, EnglandInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Thielemans, W.
;
Roman, M.
论文数: 0引用数: 0
h-index: 0
机构:
Virginia Tech, Dept Wood Sci & Forest Prod, Blacksburg, VA 24061 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Roman, M.
;
Renneckar, S.
论文数: 0引用数: 0
h-index: 0
机构:
Virginia Tech, Dept Wood Sci & Forest Prod, Blacksburg, VA 24061 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Renneckar, S.
;
Gindl, W.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Nat Resources & Appl Life Sci, Dept Mat Sci & Proc Engn, BOKU Vienna, Vienna, AustriaInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Gindl, W.
;
Veigel, S.
论文数: 0引用数: 0
h-index: 0
机构:
Wood K Plus, Competence Ctr Wood Composites & Wood Chem, Linz, AustriaInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Veigel, S.
;
Keckes, J.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Leoben, Dept Mat Phys, Erich Schmid Inst Mat Sci, Austrian Acad Sci, Leoben, AustriaInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Keckes, J.
;
Yano, H.
论文数: 0引用数: 0
h-index: 0
机构:
Kyoto Univ, Res Inst Sustainable Humanosphere, Kyoto 6110011, JapanInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Yano, H.
;
Abe, K.
论文数: 0引用数: 0
h-index: 0
机构:
Kyoto Univ, Res Inst Sustainable Humanosphere, Kyoto 6110011, JapanInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Abe, K.
;
Nogi, M.
论文数: 0引用数: 0
h-index: 0
机构:
Kyoto Univ, Res Inst Sustainable Humanosphere, Kyoto 6110011, JapanInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Nogi, M.
;
Nakagaito, A. N.
论文数: 0引用数: 0
h-index: 0
机构:
Kyoto Univ, Res Inst Sustainable Humanosphere, Kyoto 6110011, JapanInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Nakagaito, A. N.
;
Mangalam, A.
论文数: 0引用数: 0
h-index: 0
机构:
Virginia Tech, Dept Wood Sci & Forest Prod, Blacksburg, VA 24061 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Mangalam, A.
;
Simonsen, J.
论文数: 0引用数: 0
h-index: 0
机构:
Oregon State Univ, Dept Wood Sci & Engn, Corvallis, OR 97331 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Simonsen, J.
;
Benight, A. S.
论文数: 0引用数: 0
h-index: 0
机构:
Portland State Univ, Dept Chem, Portland, OR 97207 USA
Portland State Univ, Dept Phys, Portland, OR 97207 USAInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Benight, A. S.
;
Bismarck, A.
论文数: 0引用数: 0
h-index: 0
机构:
Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, Polymer & Composite Engn Grp PACE, London SW7 2AZ, EnglandInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Bismarck, A.
;
Berglund, L. A.
论文数: 0引用数: 0
h-index: 0
机构:
KTH, Wallenberg Wood Sci Ctr, Dept Fibre & Polymer Technol, S-10044 Stockholm, SwedenInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France
Berglund, L. A.
;
Peijs, T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ London, Ctr Mat Res, London E1 4NS, EnglandInt Sch Paper Print Media & Biomat Grenoble INP P, Grenoble Inst Technol, F-38402 St Martin Dheres, France