Preparation and swelling of hydrophilic magnetic microgels

被引:6
作者
Ménager, C [1 ]
Sandre, O [1 ]
Mangili, J [1 ]
Cabuil, V [1 ]
机构
[1] Univ Paris 06, CNRS, Lab Liquides Ion & Interfaces Chargees, Equipe Colloides Inorgan,UMR 7612, F-75252 Paris 05, France
关键词
magnetic fluid; microgel; hybrid particles;
D O I
10.1016/j.polymer.2004.02.018
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Hydrophilic magnetic microgels were synthesized by a free-radical polymerization in inverse emulsion. Two sizes of magnetic microgels were obtained depending on the initial droplet size of the emulsion. As the polymer matrix is a hydrogel, the novelty of this paper is that the magnetic particles are incorporated from an aqueous magnetic fluid instead of an organic one. In this paper, we underline the physicochemical aspects necessary to control the proper dispersion of the magnetic particles in the polymer matrix. The size, the magnetic content and the swelling degree of micron-sized and sub-micron sized magnetic microgels are characterized. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2475 / 2481
页数:7
相关论文
共 31 条
[1]   MAGNETIC COLLOIDAL PROPERTIES OF IONIC FERROFLUIDS [J].
BACRI, JC ;
PERZYNSKI, R ;
SALIN, D ;
CABUIL, V ;
MASSART, R .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1986, 62 (01) :36-46
[2]   Cell internalization of anionic maghemite nanoparticles: Quantitative effect on magnetic resonance imaging [J].
Billotey, C ;
Wilhelm, C ;
Devaud, M ;
Bacri, JC ;
Bittoun, J ;
Gazeau, F .
MAGNETIC RESONANCE IN MEDICINE, 2003, 49 (04) :646-654
[3]  
Elaissari A, 1999, [French Patent, French Patent], Patent No. 2800635
[4]  
Erdem B, 2000, J POLYM SCI POL CHEM, V38, P4431, DOI 10.1002/1099-0518(20001215)38:24<4431::AID-POLA120>3.0.CO
[5]  
2-Y
[6]  
Erdem B, 2000, J POLYM SCI POL CHEM, V38, P4441, DOI 10.1002/1099-0518(20001215)38:24<4441::AID-POLA130>3.0.CO
[7]  
2-U
[8]   VERY LOW FREQUENCY INTEGRATING VIBRATING SAMPLE MAGNETOMETER (VLFVSM) WITH HIGH DIFFERENTIAL SENSITIVITY IN HIGH DC FIELDS [J].
FONER, S ;
MCNIFF, EJ .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1968, 39 (02) :171-&
[9]   Designing magnetic composite materials using aqueous magnetic fluids [J].
Galicia, JA ;
Sandre, O ;
Cousin, F ;
Guemghar, D ;
Ménager, C ;
Cabuil, V .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (15) :S1379-S1402
[10]  
Hoffmann D., 2001, MAGNETOHYDRODYNAMICS, V37, P217