Comment on "Merging of the α and β relaxations in polybutadiene:: A neutron spin echo and dielectric study"

被引:31
作者
Donth, E [1 ]
Schröter, K [1 ]
Kahle, S [1 ]
机构
[1] Univ Halle, Fachbereich Phys, D-06099 Halle, Saale, Germany
来源
PHYSICAL REVIEW E | 1999年 / 60卷 / 01期
关键词
D O I
10.1103/PhysRevE.60.1099
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The evaluation method of dielectric data based on a Williams product ansatz [A. Arbe, D. Richter, J. Colmenero, and B. Farago, Phys. Rev. E 54, 3853 (1996)] is not suited to the crossover region of the dynamic glass transition. This method is insensitive to the shape, position, or even existence of at least one of the relaxation functions if, in the extrapolation from below to above the crossover region, the two processes cross or approach one another. Since a crossover region without any particular change in the relaxation mechanism of these processes can in fact be adjusted by this method, better dielectric data for polybutadiene in the gigahertz frequency region are needed to determine whether or not there are peculiarities in the dielectric function. It would be an odd assumption that the many particularities in the crossover region in other instances are not reflected in the dielectric response. [S1063-651X(99)02607-0].
引用
收藏
页码:1099 / 1102
页数:4
相关论文
共 13 条
  • [1] Crossover region of dynamic glass transition in poly(n-hexyl methacrylate) by heat capacity spectroscopy
    Beiner, M
    Kahle, S
    Hempel, E
    Schröter, K
    Donth, E
    [J]. MACROMOLECULES, 1998, 31 (25) : 8973 - 8980
  • [2] Two calorimetrically distinct parts of the dynamic glass transition
    Beiner, M
    Kahle, S
    Hempel, E
    Schroter, K
    Donth, E
    [J]. EUROPHYSICS LETTERS, 1998, 44 (03): : 321 - 327
  • [3] MOLECULAR COOPERATIVITY AGAINST LOCALITY AT GLASS-TRANSITION ONSET IN POLY(N-BUTYL METHACRYLATE)
    GARWE, F
    SCHONHALS, A
    BEINER, M
    SCHROTER, K
    DONTH, E
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 1994, 6 (35) : 6941 - 6945
  • [4] Gnedenko BV., 1962, The theory of probability, V2nd ed
  • [5] GLASS-TRANSITION AND SECONDARY RELAXATIONS IN MOLECULAR LIQUIDS AND CRYSTALS
    JOHARI, GP
    [J]. ANNALS OF THE NEW YORK ACADEMY OF SCIENCES, 1976, 279 (OCT15) : 117 - 140
  • [6] Glass-transition cooperativity onset in a series of random copolymers poly(n-butyl methacrylate-stat-styrene)
    Kahle, S
    Korus, J
    Hempel, E
    Unger, R
    Horing, S
    Schroter, K
    Donth, E
    [J]. MACROMOLECULES, 1997, 30 (23) : 7214 - 7223
  • [7] Kolmogorov A. N., 1950, Foundations of the theory of probability
  • [8] Temperature dependence of alpha glass transition cooperativity
    Korus, J
    Hempel, E
    Beiner, M
    Kahle, S
    Donth, E
    [J]. ACTA POLYMERICA, 1997, 48 (09) : 369 - 378
  • [9] WHATS WRONG WITH THE MODULI BROWN,CHARLEY - OR GET THE H OUT AND GO TO L
    PLAZEK, DJ
    [J]. JOURNAL OF RHEOLOGY, 1992, 36 (08) : 1671 - 1690
  • [10] FRACTAL TIME IN CONDENSED MATTER
    SHLESINGER, MF
    [J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1988, 39 : 269 - 290