Highly efficient, selective, and general method for the preparation of meridional homo- and heteroleptic tris-cyclometalated iridium complexes

被引：49

作者：

Huo, SQ ^{[1
]}

Deaton, JC ^{[1
]}

Rajeswaran, M ^{[1
]}

Lenhart, WC ^{[1
]}

机构：

[1] Eastman Kodak Co, Res & Dev, Rochester, NY 14650 USA

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 08期

关键词：

D O I：

10.1021/ic060089v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A highly efficient and general method based on transmetalation with an organozinc reagent is developed for selective preparation of homo- and heteroleptic meridional tris-cyclometalated iridium complexes. The molecular structure of mer-Ir(1-piq)(2)(PPY) (2) has been determined by a single-crystal X-ray diffraction analysis. The emission properties of a series of meridional complexes are reported.

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页码：3155 / 3157

页数：3

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