Microstructural evolution in spray-formed and melt-spun Al85Nd5Ni10 bulk hybrid composites

被引:14
作者
Guo, M. L. Ted
Tsao, Chi Y. A.
Huang, J. C.
Jang, J. S. C.
机构
[1] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 70101, Taiwan
[2] Natl Sun Yat Sen Univ, Inst Mat Sci & Engn, Kaohsiung 804, Taiwan
[3] I Shou Univ, Dept Mat Sci & Engn, Kaohsiung 840, Taiwan
关键词
composites; nanostructured intermetallics; twinning; rapid solidification processing; electron microscopy; transmission;
D O I
10.1016/j.intermet.2006.01.041
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Microstructure evolutions in the spray-formed and melt-spun Al85Nd5Ni10 alloys were studied. The spray forming process has shown to be capable of directly producing a bulk scale Al85Nd5Ni10 hybrid composite consisting of amorphous and nanostructured phases without the need of using an amorphous precursor. The spray-formed overspray flakes were partially amorphous, and the amorphous phase came from the undercooled liquid droplets upon deposition. The as-spray-formed deposit was completely crystallized due to the devitrification of the retained amorphous phase to nanoscale secondary crystals upon deposition. In the deposit and flake, the primary crystals were micro-scaled Al6NdNi2, and the secondary crystals devitrified from the amorphous phase during spray forming process were nanoscaled Al3Ni and Al6NdNi2, dispersed in nanoscaled alpha-Al matrix. The completely devitrified melt-spun ribbon composite consisted of secondary crystals Al3Ni, Al11Nd3 and Al6NdNi2 with nanoscale sizes, dispersed in the nanoscaled a-Al matrix. Deformation twins were observed in the primary Al6NdNi2 crystal in the as-spray-formed flake and deposit, but were not found in the secondary Al6NdNi2 crystals in the completely devitrified ribbon. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1069 / 1074
页数:6
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