Development of in situ scanning electron microscope system for real time observation of metal deposition from ionic liquid

被引：52

作者：

Arimoto, Satoshi ^{[1
,3
]}

Kageyama, Hitoshi ^{[1
,3
]}

Torimoto, Tsukasa ^{[2
,3
]}

Kuwabata, Susumu ^{[1
,3
]}

机构：

[1] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Crystalline Mat Sci, Nagoya, Aichi 4648603, Japan

[3] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2008年 / 10卷 / 12期

关键词：

In situ observation; Ionic liquid; Scanning electron microscopy; Silver deposition; Energy dispersive X-ray fluorescence analysis;

D O I：

10.1016/j.elecom.2008.10.003

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Based on our previous finding that room temperature ionic liquid (RTIL) can be observed by scanning electron microscopy (SEM) without charging of the liquid, a specifically designed electrochemical cell has been developed to observe electrochemical metal deposition from RTIL in real time by SEM. The cell was fabricated employing a fluorine doped tin oxide transparent glass, whose surface was divided into three electrodes. Then, the effectiveness of the fabricated cell was confirmed by demonstrating silver deposition form RTIL of 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (BMI-TFSI) containing Ag-TFSI, which gave growth of granular and dendritic forms of Ag deposit. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1901 / 1904

页数：4

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