Kinetics of dispersion polymerization of styrene in ethanol .2. Model validation

被引：25

作者：

Ahmed, SF

Poehlein, GW

机构：

[1] School of Chemical Engineering, Georgia Institute of Technology, Atlanta

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1997年 / 36卷 / 07期

关键词：

D O I：

10.1021/ie960506j

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Predictions of monomer conversion, polymerization rate, and evolution of particle size distribution during seeded batch and continuous dispersion polymerization obtained from simulation are compared to experimental results. An understanding of the kinetic mechanisms governing the relative prevalence of solution and microbulk polymerization has been gained. Estimates of parameters in the radical transport rate coefficient models compare favorably-with values reported in the literature.

引用

收藏

页码：2605 / 2615

页数：11

相关论文

共 11 条

[1] HYDROXYPROPYL CELLULOSE (HPC)-STABILIZED DISPERSION POLYMERIZATION OF STYRENE IN POLAR-SOLVENTS - EFFECT OF REACTION PARAMETERS [J].

CHEN, Y ;

YANG, HW .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1992, 30 (13) :2765-2772

[2]

DEADY M, 1993, MAKROMOL CHEM, V194, P1691

[3] MODELING POLY(VINYL ALCOHOL)-STABILIZED VINYL-ACETATE EMULSION POLYMERIZATION .2. COMPARISON WITH EXPERIMENT [J].

GILMORE, CM ;

POEHLEIN, GW ;

SCHORK, FJ .

JOURNAL OF APPLIED POLYMER SCIENCE, 1993, 48 (08) :1461-1473

[4] PARTICLE NUCLEATION IN EMULSION POLYMERIZATION .1. THEORY FOR HOMOGENEOUS NUCLEATION [J].

HANSEN, FK ;

UGELSTAD, J .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1978, 16 (08) :1953-1979

[5] KINETIC-ANALYSIS OF SEEDED EMULSION POLYMERIZATION OF VINYL-ACETATE [J].

LANGE, DM ;

POEHLEIN, GW ;

HAYASHI, S ;

KOMATSU, A ;

HIRAI, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (06) :785-792

[6] PARTICLE-SIZE CONTROL IN DISPERSION POLYMERIZATION OF POLYSTYRENE [J].

LOK, KP ;

OBER, CK .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1985, 63 (01) :209-216

[7]

LU YY, 1988, THESIS LEHIGH U BETH

[8] KINETICS AND MECHANISMS OF UNSEEDED EMULSION POLYMERIZATION OF METHYL-METHACRYLATE [J].

NOMURA, M ;

FUJITA, K .

POLYMER REACTION ENGINEERING, 1994, 2 (04) :317-345

[9] DIFFUSION-CONTROLLED VINYL POLYMERIZATION .4. COMPARISON OF THEORY AND EXPERIMENT [J].

SOH, SK ;

SUNDBERG, DC .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1982, 20 (05) :1345-1371

[10] AUTOACCELERATION EFFECT IN FREE-RADICAL POLYMERIZATION - A COMPARISON OF THE CCS AND MH MODELS [J].

VIVALDOLIMA, E ;

HAMIELEC, AE ;

WOOD, PE .

POLYMER REACTION ENGINEERING, 1994, 2 (1-2) :17-85