Practical and catalytic synthesis of 1,5-anhydrohex-1-en-3-uloses

被引：26

作者：

Hayashi, M ^{[1
]}

Yamada, K ^{[1
]}

Arikita, O ^{[1
]}

机构：

[1] Yamaguchi Univ, Fac Sci, Dept Chem, Yamaguchi 7538512, Japan

来源：

TETRAHEDRON | 1999年 / 55卷 / 28期

关键词：

carbohydrates; glycals; oxidation; palladium catalyst;

D O I：

10.1016/S0040-4020(99)00426-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A practical and catalytic method for the preparation of 15-anhydrohex-1-en-3-uloses based on hydrogen transfer of D-glucals by catalytic amount of palladium complex in the presence of olefinic compounds such as ethylene and vinyl acetate has been disclosed. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：8331 / 8340

页数：10

共 18 条

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