Mixing Behavior at the solid/liquid interface: Binary monolayers of linear alcohols adsorbed on graphite

被引：26

作者：

Messe, L

Clarke, SM

Arnold, T

Dong, C

Thomas, RK

Inaba, A

机构：

[1] Univ Cambridge, BP Inst, Cambridge CB3 0EZ, England

[2] Univ Cambridge, Dept Chem, Cambridge CB3 0EZ, England

[3] Univ Oxford, Phys & Theoret Chem Lab, Oxford, England

[4] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 560, Japan

来源：

LANGMUIR | 2002年 / 18卷 / 10期

关键词：

D O I：

10.1021/la0118762

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Differential scanning calorimetry combined with neutron diffraction has been used to characterize the mixing behavior of crystalline monolayers of binary mixtures of linear alcohols adsorbed from solution to a graphite surface. The results indicate that for pairs of alcohols with alkyl chain lengths of C5-C11 and which differ in length by two or more methylene groups there is phase separation in the mixed monolayers. These results are shown to be in agreement with a recent quantitative model of phase separation in two-dimensional physisorbed monolayers.

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收藏

页码：4010 / 4013

页数：4

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