EQCM study of polypyrrole modified electrodes doped with Keggin-type heteropolyanion for cation detection

被引：35

作者：

Abrantes, LM

Cordas, CM

Vieil, E

机构：

[1] Univ Lisbon, Fac Ciencias, Dept Quim & Bioquim, CECUL, P-1749016 Lisbon, Portugal

[2] CEA Grenoble, Lab Electrochim Mol, UMR 5819, F-38054 Grenoble 9, France

来源：

ELECTROCHIMICA ACTA | 2002年 / 47卷 / 09期

关键词：

polypyrrole; Keggin-type heteropolyanion; cyclic voltammetry; electrochemical quartz crystal microbalance; cation detection;

D O I：

10.1016/S0013-4686(01)00859-3

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The incorporation of a Keggin-type heteropolyanion, the phosphotungstate ([PW12O40](3-)), into polypyrrole has been achieved during the electrochemical preparation of the polymer films in aqueous solution. The redox behaviour of these modified electrodes is described by using cyclic voltammetry (CV) and electrochemical quartz crystal microbalance (EQCM). The data allowed to estimate the doping level that indicates the extent of the heteropolyanion insertion. It is found that the polymer films, in aqueous solution, exhibit sensibility to cations, namely to Na+. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1481 / 1487

页数：7

共 18 条

[1] Electrochemical behaviour of polyaniline films doped with heteropolyanions of Keggin structure [J].

Barth, M ;

Lapkowski, M ;

Lefrant, S .

ELECTROCHIMICA ACTA, 1999, 44 (12) :2117-2123

[2] POLYPYRROLE AND POLY(N-METHYLPYRROLE) FILMS DOPED WITH KEGGIN-TYPE HETEROPOLYANIONS - PREPARATION AND PROPERTIES [J].

BIDAN, G ;

GENIES, EM ;

LAPKOWSKI, M .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 251 (02) :297-306

[3] EXPERIMENTAL ASPECTS OF USE OF THE QUARTZ CRYSTAL MICROBALANCE IN SOLUTION [J].

BRUCKENSTEIN, S ;

SHAY, M .

ELECTROCHIMICA ACTA, 1985, 30 (10) :1295-1300

[4] EQCM studies of polypyrrole films. 1. Exposure to aqueous sodium tosylate solutions under thermodynamically permselective conditions [J].

Bruckenstein, S ;

Brzezinska, K ;

Hillman, AR .

ELECTROCHIMICA ACTA, 2000, 45 (22-23) :3801-3811

[5] PREPARATION AND PROPERTIES OF POLYPYRROLE FILM DOPED WITH A DAWSON-TYPE HETEROPOLYANION [J].

DONG, SJ ;

LIU, MJ .

ELECTROCHIMICA ACTA, 1994, 39 (07) :947-951

[6] Combined electrochemical quartz crystal microbalance (EQCM) and probe beam deflection (PBD): validation of the technique by a study of silver ion mass transport [J].

Henderson, MJ ;

Hillman, AR ;

Vieil, E ;

Lopez, C .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 458 (1-2) :241-248

[7] THERMODYNAMIC CHANGES IN ION AND SOLVENT POPULATIONS ACCOMPANYING REDOX SWITCHING IN POLYVINYLFERROCENE FILMS [J].

HILLMAN, AR ;

LOVEDAY, DC ;

BRUCKENSTEIN, S .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 274 (1-2) :157-166

[8] DOPING DEDOPING OF POLYPYRROLE - A STUDY USING CURRENT-MEASURING AND RESISTANCE-MEASURING TECHNIQUES [J].

JOHN, R ;

WALLACE, GG .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 354 (1-2) :145-160

[9] EQCM MONITORING OF CHARGE-TRANSPORT PROCESSES IN POLYANILINE FILMS DOPED WITH 12-SILICOMOLYBDIC HETEROPOLYANION [J].

KEITA, B ;

MAHMOUD, A ;

NADJO, L .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 386 (1-2) :245-251

[10] SYNTHESIS OF POLYPYRROLE AND POLYTHIOPHENE IN AQUEOUS-SOLUTION OF KEGGIN-TYPE STRUCTURE HETEROPOLYANIONS [J].

LAPKOWSKI, M ;

BIDAN, G ;

FOURNIER, M .

SYNTHETIC METALS, 1991, 41 (1-2) :407-410

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