Slow Magnetization Relaxation in Unprecedented Mn4IIIDy3III and Mn4IIIDy5III Clusters from the Use of N-Salicylidene-o-aminophenol

被引：45

作者：

Alexandropoulos, Dimitris I. ^{[1
]}

Nguyen, Tu N. ^{[2
]}

Cunha-Silva, Luis ^{[3
,4
]}

Zafiropoulos, Theodoros F. ^{[5
]}

Escuer, Albert ^{[6
]}

Christou, George ^{[2
]}

Stamatatos, Theocharis C. ^{[1
]}

机构：

[1] Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada

[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[3] Univ Porto, REQUIMTE, P-4169007 Oporto, Portugal

[4] Univ Porto, Dept Chem & Biochem, Fac Sci, P-4169007 Oporto, Portugal

[5] Univ Patras, Dept Chem, Patras 26504, Greece

[6] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 03期

基金：

美国国家科学基金会;

关键词：

SINGLE-MOLECULE MAGNETS; COMPLEXES; MANGANESE; LIGANDS; HYSTERESIS; CRYSTAL;

D O I：

10.1021/ic302505p

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

The first use of N-salicylidene-o-aminophenol in 3d/4f chemistry has led to (Mn4Dy5III)-Dy-III and (Mn4Dy3III)-Dy-III clusters with unprecedented metal topologies and stoichiometries; both compounds exhibit out-of-phase signals indicative of the slow magnetization relaxation of a single-molecule magnet.

引用

页码：1179 / 1181

页数：3

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