Role of calcium ions as doped-hole attractors in destabilizing charge-ordered states in Mn perovskites -: art. no. 172410

被引:10
作者
Alonso, J
Arroyo, A
González-Calbet, JM
Vallet-Regí, M
Martínez, JL
Rojo, JM
Hernando, A
机构
[1] UCM, CSIC, RENFE, Inst Magnetismo Aplicado, Madrid 28230, Spain
[2] CSIC, ICMM, E-28049 Madrid, Spain
[3] UCM, Dept Fis Mat, Madrid 28040, Spain
关键词
D O I
10.1103/PhysRevB.64.172410
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Magnetization and resistivity measurements have been performed in (La1-xCax)(z)MnO3-delta perovskites as a function of x, z, and delta around the charge-ordered state. Fifty percent of Ca ions stabilize the charge-ordered state even for Mn4+ as low as 40% whereas reducing that impurity concentration to 35% results in a conducting ferromagnetic state even for 50% of Mn4+ ions. A model is proposed in which Ca ions act not only as suppliers of holes but as attractors of doped-in holes.
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页数:4
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