Gigas growth of carbon nanotubes

被引:21
作者
Kumar, Mukul [1 ]
Ando, Yoshinori [1 ]
机构
[1] Meijo Univ, Tempaku Ku, Nagoya, Aichi 4688502, Japan
关键词
carbon nanotubes; camphor; chemical vapour deposition; green nanotechnology; gigas growth;
D O I
10.14429/dsj.58.1670
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
An exceptionally high yield of carbon nanotubes (CNTs) has been achieved by chemical vapour deposition (CVD) of camphor over zeolite support. A simple 30 min CVD of 12 g camphor over Fe-Co-impregnated zeolite at 650 degrees C in an academic laboratory setup, yields 6 g multiwalled CNTs of dia similar to 10 nm with an as-grown purity of similar to 88 per cent. Owing to the enormous CNT growth, the zeolite bed inflates by 1000 wt per cent and 10,000 vol per cent. Camphor-to-CNT production efficiency is 50 per cent and net carbon-to-CNT conversion efficiency is 61per cent. These figures are incomparably higher than that of any CNT precursor by any method. Hence it is called 'gigas growth'. The technique greatly complies with the principles of green chemistry, and thus sets an example of an environment-friendly nanotechnology.
引用
收藏
页码:496 / 503
页数:8
相关论文
共 25 条
[1]   Carbon nanotubes by spray pyrolysis of turpentine oil at different temperatures and their studies [J].
Afre, Rakesh A. ;
Soga, T. ;
Jimbo, T. ;
Kumar, Mukul ;
Ando, Y. ;
Sharon, M. ;
Somani, Prakash R. ;
Umeno, M. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 96 (1-3) :184-190
[2]  
Anastas PT., 1998, Principles of green chemistry
[3]  
Cassell AM, 1999, J PHYS CHEM B, V103, P6484, DOI 10.1021/jp990957sCCC:$18.00
[4]   CVD synthesis of high-purity multiwalled carbon nanotubes using CaCO3 catalyst support for large-scale production [J].
Couteau, E ;
Hernadi, K ;
Seo, JW ;
Thiên-Nga, L ;
Mikó, C ;
Gaál, R ;
Forró, L .
CHEMICAL PHYSICS LETTERS, 2003, 378 (1-2) :9-17
[5]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[6]   Controlling the diameter distribution of carbon nanotubes grown from camphor on a zeolite support [J].
Kumar, M ;
Ando, Y .
CARBON, 2005, 43 (03) :533-540
[7]   Single-wall and multi-wall carbon nanotubes from camphor - a botanical hydrocarbon [J].
Kumar, M ;
Ando, Y .
DIAMOND AND RELATED MATERIALS, 2003, 12 (10-11) :1845-1850
[8]   Field emission from camphor-pyrolyzed carbon nanotubes [J].
Kumar, M ;
Kakamu, K ;
Okazaki, T ;
Ando, Y .
CHEMICAL PHYSICS LETTERS, 2004, 385 (3-4) :161-165
[9]   Camphor-a botanical precursor producing garden of carbon nanotubes [J].
Kumar, M ;
Ando, Y .
DIAMOND AND RELATED MATERIALS, 2003, 12 (3-7) :998-1002
[10]   A simple method of producing aligned carbon nanotubes from an unconventional precursor - Camphor [J].
Kumar, M ;
Ando, Y .
CHEMICAL PHYSICS LETTERS, 2003, 374 (5-6) :521-526