Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity

被引:777
作者
Budd, PM
Elabas, ES
Ghanem, BS
Makhseed, S
McKeown, NB
Msayib, KJ
Tattershall, CE
Wang, D
机构
[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
[2] Univ Wales Coll Cardiff, Sch Chem, Cardiff CF10 3TB, S Glam, Wales
关键词
D O I
10.1002/adma.200306053
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A polymer with a rigid, randomly contorted molecular structure (see Figure), incorporating fused rings connected by spiro-centres, may be precipitated or cast from solution to give microporous powders and membranes stable up to temperatures of 350degreesC, with apparent surface areas > 600 m(2) g(-1). Organophilic membranes may be formed, as demonstrated by the separation of phenol from water by pervaporation.
引用
收藏
页码:456 / +
页数:5
相关论文
共 19 条
  • [1] Tailored porous materials
    Barton, TJ
    Bull, LM
    Klemperer, WG
    Loy, DA
    McEnaney, B
    Misono, M
    Monson, PA
    Pez, G
    Scherer, GW
    Vartuli, JC
    Yaghi, OM
    [J]. CHEMISTRY OF MATERIALS, 1999, 11 (10) : 2633 - 2656
  • [2] Performance of PDMS and organofunctionalised PDMS membranes for the pervaporative recovery of organics from aqueous streams
    Bennett, M
    Brisdon, BJ
    England, R
    Field, RW
    [J]. JOURNAL OF MEMBRANE SCIENCE, 1997, 137 (1-2) : 63 - 88
  • [3] Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials
    Budd, PM
    Ghanem, BS
    Makhseed, S
    McKeown, NB
    Msayib, KJ
    Tattershall, CE
    [J]. CHEMICAL COMMUNICATIONS, 2004, (02) : 230 - 231
  • [4] A nanoporous network polymer derived from hexaazatrinaphthylene with potential as an adsorbent and catalyst support
    Budd, PM
    Ghanem, B
    Msayib, K
    McKeown, NB
    Tattershall, C
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (11) : 2721 - 2726
  • [5] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks
    Eddaoudi, M
    Moler, DB
    Li, HL
    Chen, BL
    Reineke, TM
    O'Keeffe, M
    Yaghi, OM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) : 319 - 330
  • [6] METHOD FOR THE CALCULATION OF EFFECTIVE PORE-SIZE DISTRIBUTION IN MOLECULAR-SIEVE CARBON
    HORVATH, G
    KAWAZOE, K
    [J]. JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1983, 16 (06) : 470 - 475
  • [7] Kesting R.E., 1993, POLYM GAS SEPARATION
  • [8] Organophilic pervaporation: prospects and performance
    Lipnizki, F
    Hausmanns, S
    Ten, PK
    Field, RW
    Laufenberg, G
    [J]. CHEMICAL ENGINEERING JOURNAL, 1999, 73 (02) : 113 - 129
  • [9] Porphyrin-based nanoporous network polymers
    McKeown, NB
    Hanif, S
    Msayib, K
    Tattershall, CE
    Budd, PM
    [J]. CHEMICAL COMMUNICATIONS, 2002, (23) : 2782 - 2783
  • [10] Phthalocyanine-based nanoporous network polymers
    McKeown, NB
    Makhseed, S
    Budd, PM
    [J]. CHEMICAL COMMUNICATIONS, 2002, (23) : 2780 - 2781