Cyclopropanation of unsaturated sugars with ethyl diazoacetate

被引：55

作者：

Hoberg, JO

Claffey, DJ

机构：

[1] National Renewable Energy Laboratory, Golden, CO 80401

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 15期

关键词：

D O I：

10.1016/0040-4039(96)00335-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cyclopropanation of unsaturated sugars with ethyl diazoacetate and a metal catalyst provides ester-substituted 12-C-methylene carbohydrates in good to excellent yields, Ring opening of the cyclopropane has also been achieved providing C-2 branched glycosyl bromides. Copyright (C) 1996 Elsevier Science Ltd

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页码：2533 / 2536

页数：4

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