A facile preparation of alkyl azides from alkyl bromides and sodium azide using 18-crown-6 ether doped clay

被引：17

作者：

Varma, RS ^{[1
]}

Naicker, KP

Aschberger, J

机构：

[1] Sam Houston State Univ, Dept Chem, Huntsville, TX 77341 USA

[2] Sam Houston State Univ, Texas Res Inst Environm Studies, Huntsville, TX 77341 USA

来源：

SYNTHETIC COMMUNICATIONS | 1999年 / 29卷 / 16期

关键词：

D O I：

10.1080/00397919908086450

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A high yield synthesis of alkyl azides is described from readily accessible alkyl bromides and sodium azide using a recyclable phase transfer catalyst, 18-crown-6 ether impregnated clay.

引用

页码：2823 / 2830

页数：8

共 44 条

[1] CATALYZED-REACTIONS OF ORGANIC-MOLECULES AT CLAY SURFACES - ESTER BREAKDOWN, DIMERIZATIONS, AND LACTONIZATIONS [J].

ADAMS, JM ;

DAVIES, SE ;

GRAHAM, SH ;

THOMAS, JM .

JOURNAL OF CATALYSIS, 1982, 78 (01) :197-208

[2] SILICA IMPREGNATED WITH TETRAMETHYLAMMONIUM SALTS AS SOLID SOLID LIQUID TRIPHASE CATALYSTS [J].

ARRAD, O ;

SASSON, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (09) :2952-2954

[3] ORGANIC-REACTIONS IN A CLAY MICROENVIRONMENT [J].

BALLANTINE, JA ;

PURNELL, JH ;

THOMAS, JM .

CLAY MINERALS, 1983, 18 (04) :347-356

[4] CHEMICAL CONVERSIONS USING SHEET SILICATES - FACILE ESTER SYNTHESIS BY DIRECT ADDITION OF ACIDS TO ALKENES [J].

BALLANTINE, JA ;

DAVIES, M ;

PURNELL, H ;

RAYANAKORN, M ;

THOMAS, JM ;

WILLIAMS, KJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (01) :8-9

[5] CONFIGURATION OF CARBOHYDRATES, HYDROXY-ACIDS AND AMINO-ACIDS [J].

BREWSTER, P ;

HUGHES, ED ;

INGOLD, CK ;

RAO, PADS .

NATURE, 1950, 166 (4213) :178-179

[6]

BRUCE MG, 1995, MATER CHEM, P301

[7] ZR-CONTAINING PILLARED INTERLAYER CLAYS .2. CATALYTIC ACTIVITY FOR THE CONVERSION OF METHANOL INTO HYDROCARBONS [J].

BURCH, R ;

WARBURTON, CI .

JOURNAL OF CATALYSIS, 1986, 97 (02) :511-515

[8] SCHIZOID REACTIVITY OF N-BENZYLIDENE ANILINE TOWARD CLAY-CATALYZED CYCLO-ADDITIONS [J].

CABRAL, J ;

LASZLO, P ;

MONTAUFIER, MT .

TETRAHEDRON LETTERS, 1988, 29 (05) :547-550

[9] CHEMISTRY OF NAKED ANIONS .3. REACTIONS OF 18-CROWN-6 COMPLEX OF POTASSIUM CYANIDE WITH ORGANIC SUBSTRATES IN APROTIC ORGANIC-SOLVENTS [J].

COOK, FL ;

BOWERS, CW ;

LIOTTA, CL .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (23) :3416-3418

[10]

COREY EJ, 1975, SYNTHESIS-STUTTGART, P590

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