Experimental and theoretical evidence for the isolation of thorium hydride molecules in argon matrices

被引：52

作者：

Souter, PF

Kushto, GP

Andrews, L

Neurock, M

机构：

[1] UNIV VIRGINIA,DEPT CHEM,CHARLOTTESVILLE,VA 22901

[2] UNIV VIRGINIA,DEPT CHEM ENGN,CHARLOTTESVILLE,VA 22901

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1997年 / 101卷 / 07期

关键词：

D O I：

10.1021/jp962863d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The primary reaction products of laser-ablated thorium atoms with dihydrogen, ThH, ThH2, ThH3, and ThH4 have been isolated for the first time in an argon matrix and identified by the effects-of isotopic substitution on their infrared spectra. DFT calculations provide firm theoretical support for the spectral assignments.

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页码：1287 / 1291

页数：5

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