Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane

被引：341

作者：

Bae, Youn-Sang ^{[1
]}

Farha, Omar K. ^{[2
,3
]}

Spokoyny, Alexander M. ^{[2
,3
]}

Mirkin, Chad A. ^{[2
,3
]}

Hupp, Joseph T. ^{[2
,3
]}

Snurr, Randall Q. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[3] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 35期

关键词：

D O I：

10.1039/b805785k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Separation of CO2/CH4 mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (similar to 17) are obtained, especially in the material with open metal sites.

引用

页码：4135 / 4137

页数：3

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