The Effect of Oxygen Crossover on the Anode of a Li-O2 Battery using an Ether-Based Solvent: Insights from Experimental and Computational Studies

被引：225

作者：

Assary, Rajeev S. ^{[1
]}

Lu, Jun ^{[2
]}

Du, Peng ^{[2
]}

Luo, Xiangyi ^{[2
,4
]}

Zhang, Xiaoyi ^{[3
]}

Ren, Yang ^{[3
]}

Curtiss, Larry A. ^{[1
]}

Amine, Khalil ^{[2
]}

机构：

[1] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

[3] Argonne Natl Lab, Xray Sci Div, Argonne, IL 60435 USA

[4] Univ Utah, Dept Met Engn, Salt Lake City, UT 84112 USA

来源：

CHEMSUSCHEM | 2013年 / 6卷 / 01期

关键词：

batteries; electrochemistry; lithium; membranes; oxygen; LITHIUM-AIR BATTERIES; PERFORMANCE; REDUCTION; ELECTROLYTES; COMPOSITE;

D O I：

10.1002/cssc.201200810

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crosstown traffic: Further development of Li-O2 batteries may eventually lead to their use in transportation applications. One problem that needs to be addressed is electrolyte decomposition, which has been partially mitigated by using ether- rather than carbonate-based solvents. The influence of oxygen crossover from the cathode to the anode on electrolyte, and lithium anode, decomposition in ether-based Li-O2 batteries is investigated. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：51 / 55

页数：5

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