Characterization of plasma polymers of acrylic acid and propanoic acid

被引：82

作者：

OToole, L ^{[1
]}

Beck, AJ ^{[1
]}

Short, RD ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT MAT ENGN,LAB SURFACE & INTERFACE ANAL,SHEFFIELD S1 3JD,S YORKSHIRE,ENGLAND

来源：

MACROMOLECULES | 1996年 / 29卷 / 15期

关键词：

D O I：

10.1021/ma9518417

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Plasma polymers of acrylic (propenoic) acid and propanoic acid were prepared from inductively coupled, radio-frequency-induced plasmas excited in vapors of the starting materials. The plasma polymers were characterized by X-ray photoelectron spectroscopy (XPS), infrared reflection absorption spectroscopy (IRAS), and static secondary-ion mass spectrometry (SIMS). Detailed interpretation of the spectra allows determination of the distribution of chemical functionalites at the surface of the product and of the influence of unsaturation and plasma power on this distribution. The results are discussed in the context of previously proposed mechanisms of plasma polymerization of the compounds under investigation.

引用

页码：5172 / 5177

页数：6

共 23 条

[1] THE FORMATION OF HIGH SURFACE CONCENTRATIONS OF HYDROXYL-GROUPS IN THE PLASMA POLYMERIZATION OF ALLYL ALCOHOL [J].

AMEEN, AP ;

SHORT, RD ;

WARD, RJ .

POLYMER, 1994, 35 (20) :4382-4391

[2]

[Anonymous], 1989, HDB STATIC SECONDARY

[3]

Beamson G., 1993, Adv. Mater., V5, P778, DOI [DOI 10.1002/ADMA.19930051035, 10.1002/adma.19930051035]

[4]

BECK AL, 1995, J CHEM SOC CHEM COMM, V10, P1053

[5] ANALYSIS OF POLYMER SURFACES BY SIMS .14. ALIPHATIC-HYDROCARBONS REVISITED [J].

BRIGGS, D .

SURFACE AND INTERFACE ANALYSIS, 1990, 15 (12) :734-738

[6]

BRIGGS D, 1986, VACUUM A, V3, P1322

[7] STATIC SECONDARY-ION MASS-SPECTROMETRIC INVESTIGATION OF THE SURFACE-STRUCTURE OF ORGANIC PLASMA-DEPOSITED FILMS PREPARED FROM STABLE-ISOTOPE-LABELED PRECURSORS .1. CARBONYL PRECURSORS [J].

CHILKOTI, A ;

RATNER, BD ;

BRIGGS, D .

ANALYTICAL CHEMISTRY, 1991, 63 (15) :1612-1620

[8] STRUCTURE AND SURFACE-PROPERTIES OF PLASMA POLYMERIZED ACRYLIC-ACID LAYERS [J].

CHO, DL ;

CLAESSON, PM ;

GOLANDER, CG ;

JOHANSSON, K .

JOURNAL OF APPLIED POLYMER SCIENCE, 1990, 41 (7-8) :1373-1390

[9]

CLARK DT, 1977, J POLYM SCI POL CHEM, V15, P283

[10] SPECTRA ANALYSIS OF THE XPS CORE AND VALENCE ENERGY-LEVELS OF POLYMERS BY AN AB-INITIO MO METHOD USING SIMPLE-MODEL MOLECULES [J].

ENDO, K ;

INOUE, C ;

KOBAYASHI, N ;

AIDA, M .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1994, 55 (06) :471-478

← 1 2 3 →