First evidence for radical anions in metathesis catalysis

被引：17

作者：

Amir-Ebrahimi, V ^{[1
]}

Hamilton, JG

Nelson, J

Rooney, JJ

Thompson, JM

Beaumont, AJ

Rooney, AD

Harding, CJ

机构：

[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland

[2] Natl Univ Ireland, Dept Chem, Maynooth, Kildare, Ireland

[3] Open Univ, Dept Chem, Milton Keynes MK7 6AA, Bucks, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904619d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Grubbs' catalyst, (PCy3)(2)RuCl2(=CHPh), generates persistent radical anions on treatment with pi-acceptors such as p-benzoquinones and a remarkably wide range of dienes and even simple alkenes.

引用

页码：1621 / 1622

页数：2

共 13 条

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