End-group dynamics of fluorescently labeled dendrimers

被引：22

作者：

Wilken, R ^{[1
]}

Adams, J ^{[1
]}

机构：

[1] TECH UNIV CLAUSTHAL,INST PHYS CHEM,D-38678 CLAUSTHAL ZELLERF,GERMANY

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1997年 / 18卷 / 08期

关键词：

D O I：

10.1002/marc.1997.030180806

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The molecular dynamics of dendrimer branches were studied by observing the excimer formation of pyrenyl end-groups. By a selective synthesis only one pyrene moiety per dendron was attached, resulting in a dendrimer with 3 fluorophors per molecule. The first 3 generations of the dendrimer were synthesized by the convergent-growth approach. By time resolved measurements of the excimer and monomer fluorescence an increased mobility of the end-groups was observed.

引用

页码：659 / 665

页数：7

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