Stability of new optical pH sensing material based on cross-linked poly(vinyl alcohol) copolymer

被引：77

作者：

Cajlakovic, M

Lobnik, A

Werner, T ^{[1
]}

机构：

[1] Univ Regensburg, Inst Analyt Chem, D-93040 Regensburg, Germany

[2] Univ Maribor, Inst Text Chem, Maribor, Slovenia

来源：

ANALYTICA CHIMICA ACTA | 2002年 / 455卷 / 02期

关键词：

optical pH sensor; fluorescein; sol-gel; cross-linked poly(vinyl alcohol); fluorescence; immobilisation;

D O I：

10.1016/S0003-2670(01)01598-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Cross-linked poly(vinyl alcohol) (PVA)-silica get copolymer has been employed as a optical pH sensor substrate for immobilisation of fluorescein. Cross-linking was carried out by the sol-gel process incorporating PVA in initial sol-gel solution of tetra-methoxysilane (TMOS) under acidic conditions. Three dimensional network formation could be achieved using compositions of PVA/TMOS = 80-90/20-10 vol.% to result in crack-free films. The fluorescent sensor layers were prepared by dip-coating of gel solution onto glass slides. The dynamic fluorescence response towards different pH values was investigated in terms of the influence of sample ionic strength, membrane composition as well as age of sol-gel layers. Depending on the composition of the matrix pK(a) values of 6.50, 6.68 and 7.06 were found 18 days after continues storage in buffer. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：207 / 213

页数：7

共 37 条

[1]

ADLER A, 1999, Patent No. 005922612A

[2]

[Anonymous], PMSE PREPR

[3] ELECTRONIC ABSORPTION AND FLUORESCENCE-SPECTRA OF XANTHENE DYES IN POLYMERS [J].