Hydrothermal synthesis of novel sandwich-like structured ZnS/octylamine hybrid nanosheets

被引：45

作者：

Li, JP ^{[1
]}

Xu, Y ^{[1
]}

Wu, D ^{[1
]}

Sun, YH ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China

来源：

SOLID STATE COMMUNICATIONS | 2004年 / 130卷 / 09期

关键词：

semiconductors; nanostructures; layered compounds; organic/inorganic hybrid material;

D O I：

10.1016/j.ssc.2004.03.016

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Novel sandwich-like structured zinc sulfide (ZnS)/octylamine (OA) hybrid nanosheets with exclusively sheet-like morphology were synthesized for the first time via a mild hydrothermal route using OA as structure-directing agent. The assynthesized products were characterized by the X-ray diffraction, transmission electron microscopy, scan electron microscopy, energy dispersive analyses of X-rays, thermogravimetric analysis, and ultraviolet and visible absorption spectroscopy. The results showed that OA molecules were intercalated between wurtzite ZnS layers. As revealed from optical absorption measurements, the hybrid nanosheets exhibits strong quantum confinement effect with a great blue shift in the band gap. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：619 / 622

页数：4

共 24 条

[1] Study of the growth of ZnS nanoparticles in water/AOT/n-heptane microemulsions by UV-absorption spectroscopy [J].