Improved efficiency of the ruthenium-catalyzed redox isomerization of allyl alcohols

被引：74

作者：

Slugovc, C ^{[1
]}

Rüba, E ^{[1
]}

Schmid, R ^{[1
]}

Kirchner, K ^{[1
]}

机构：

[1] Vienna Univ Technol, Inst Inorgan Chem, A-1060 Vienna, Austria

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 20期

关键词：

D O I：

10.1021/om990264y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new complexes [RuCp(PR3)(CH3CN)(2)]PF6 (R = Ph, Me, Cy) are highly active catalysts for the redox isomerization. of allyl alcohols to give the corresponding carbonyl compounds in high yields and high efficiency. ALL reactions proceed under mild reaction conditions. In some cases, allylations of the carbonyl compounds could be achieved in, a tandem catalytic process.

引用

页码：4230 / 4233

页数：4

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