Epoxidation of alkenes through oxygen activation over a bifunctional CuO/Al2O3 catalyst

被引：29

作者：

Scotti, Nicola ^{[1
]}

Ravasio, Nicoletta ^{[1
]}

Zaccheria, Federica ^{[1
]}

Psaro, Rinaldo ^{[1
]}

Evangelisti, Claudio ^{[1
]}

机构：

[1] ISTM CNR, I-20133 Milan, Italy

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 19期

关键词：

LIQUID-PHASE OXIDATION; PROPYLENE EPOXIDATION; SELECTIVE OXIDATION; OLEFIN EPOXIDATION; COPPER; ALCOHOLS; CUMENE; COMPLEXES; ALDEHYDES; EFFICIENT;

D O I：

10.1039/c3cc37843h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The epoxidation of alkenes was carried out over a CuO/Al2O3 catalyst using cumene as an oxygen carrier, through a one-pot reaction, giving high conversion and selectivity with different substrates. Trans-beta-methylstyrene gave the corresponding epoxide in 95% yield after 3 h.

引用

收藏

页码：1957 / 1959

页数：3

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