The physical organic chemistry of very high-spin polyradicals

被引:89
作者
Rajca, A [1 ]
机构
[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA
来源
ADVANCES IN PHYSICAL ORGANIC CHEMISTRY, VOL 40 | 2005年 / 40卷
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0065-3160(05)40004-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This review outlines the design and characterization of very high-spin polyradicals. The rational, "bottom-up" design and characterization of polyarylmethyl polyradicals with increasing number of exchange coupled unpaired electron spins are described. © 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:153 / 199
页数:47
相关论文
共 91 条
[1]  
Iwamura H., High-spin organic molecules and spin alignement in organic molecular assemblies, Adv. Phys. Org. Chem., 26, pp. 179-253, (1990)
[2]  
Dougherty D.A., Spin control in organic molecules, Acc. Chem. Res., 24, pp. 88-94, (1991)
[3]  
Rajca A., Organic diradicals and polyradicals: from spin coupling to magnetism?, Chem. Rev., 94, pp. 871-893, (1994)
[4]  
Magnetic Properties of Organic Materials, (1999)
[5]  
Crayston J.A., Devine J.N., Walton J.C., Conceptual and synthetic strategies for the preparation of organic magnets, Tetrahedron, 56, pp. 7829-7857, (2000)
[6]  
Rajca A., Wongsriratanakul J., Rajca S., Magnetic ordering in an organic polymer, Science, 294, pp. 1503-1505, (2001)
[7]  
Rajca A., From high-spin organic molecules to polymers with magnetic ordering, Chem. Eur. J., 8, pp. 4834-4841, (2002)
[8]  
Lis T., Acta Crystallogr. Sect. B, B36, pp. 2042-2046, (1980)
[9]  
Sessoli R., Gatteshi D., Caneshi A., Novak M.A., Magnetic bistability in a metal-ion cluster, Nature, 365, pp. 141-143, (1993)
[10]  
Friedman J.R., Sarachik M.P., Tejada J., Ziolo R., Macroscopic measurement of resonant magnetization tunneling in high-spin molecules, Phys. Rev. Lett., 76, pp. 3830-3833, (1996)