Raman study on intermolecular and ionic interactions in gel electrolytes

被引：11

作者：

Adebahr, J

Gavelin, P

Ostrovskii, D ^{[1
]}

Torell, LM

Wesslen, B

机构：

[1] Chalmers, Dept Phys, SE-41296 Gothenburg, Sweden

[2] Lund Univ, SE-22100 Lund, Sweden

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1999年 / 482卷

关键词：

Raman scattering; gel electrolyte; intermolecular interaction;

D O I：

10.1016/S0022-2860(98)00686-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Raman spectroscopy was applied to investigate the intermolecular interactions in multi-component gel electrolytes consisting of ethylene carbonate and propylene carbonate, (EC-PC) mixed solvent, lithium salt and PMMA polymeric matrix. It is shown that triflate anions tend to essential aggregation in the EC/PC solvent, which results in a worsening of both mechanical and conductive properties of the gel. It is also found that PMMA-based gels with low salt concentration show an obvious macroscopic phase separation, and the spectroscopic characterization of the different phases is presented. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：487 / 490

页数：4

共 8 条

[1] Triflate ion association in plasticized polymer electrolytes [J].