Influence of chlorine ions in Pt/Al2O3 catalysts for methane total oxidation

Residual chlorine ions on a Pt/Al2O3 catalyst surface prepared from chlorine-containing precursors appear to inhibit the total oxidation of methane. At 450 degrees C, as chlorine is eliminated with time on stream, the reaction rate increases despite the sintering of the platinum particles. The steady state reaction rate which is reached after 60 h is identical to that obtained with a catalyst prepared from a precursor containing no chlorine. Whether chlorine is present or not in the initial state of the catalyst does not appear to have an influence on the evolution of the platinum particle size.