2-amidopyrroles and 2,5-diamidopyrroles as simple anion binding agents

被引:94
作者
Gale, PA [1 ]
Camiolo, S [1 ]
Tizzard, GJ [1 ]
Chapman, CP [1 ]
Light, ME [1 ]
Coles, SJ [1 ]
Hursthouse, MB [1 ]
机构
[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
关键词
D O I
10.1021/jo016020g
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Four new 2-amidopyrroles and 2,5-diamidopyrroles have been synthesized and their anion complexation properties investigated. The crystal structures of these receptors have been elucidated and reveal hydrogen bonding in the solid state leading to dimer and network formation. Selectivity for oxo-anions has been demonstrated by H-1 NMR titration techniques.
引用
收藏
页码:7849 / 7853
页数:5
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