A facile synthesis of amides by selective hydration of nitriles using modified natural phosphate and hydroxyapatite as new catalysts

被引:53
作者
Bazi, F
El Badaoui, H
Tamani, S
Sokori, S
Solhy, A
Macquarrie, DJ
Sebti, S
机构
[1] Univ Hassan II Mohammedia, Fac Sci Ben MSik, Lab Chim Organ Catalyse & Environm, Casablanca 20702, Morocco
[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
关键词
heterogeneous catalysis; hydroxyapatite; natural phosphate; selective hydration;
D O I
10.1016/j.apcata.2005.12.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The selective hydration of several nitriles has been accomplished using sodium nitrate modified natural phosphate (NP) and hydroxyapatite (HAP). The corresponding amides were obtained efficiently and selectively in good yields. This reaction was carried out under eco-friendly conditions using water in the absence of organic solvents. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:211 / 214
页数:4
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