Amphiphilic diblock copolymer compatibilizers and their effect on the morphology and performance of polythiophene:: Fullerene solar cells

被引：365

作者：

Sivula, K

Ball, ZT

Watanabe, N

Fréchet, JMJ

机构：

[1] Univ Calif Berkeley, Dept Chem Engn, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA

[3] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

ADVANCED MATERIALS | 2006年 / 18卷 / 02期

关键词：

D O I：

10.1002/adma.200501787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A diblock copolymer containing a fullerene(C-60)-rich block an a poly(3-hexylthiophene) block functions as a compatibilizer in poly (3-hexylthiophene):[6,6]-phenyl C-61-butyric acid methyl ester (P3HT:PCBM) blends. The copolymer is used to probe the impact of morphology and phase-segregation kinetics on the performance of P3HT:PCBM-based solar cells.

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页码：206 / +

页数：6

相关论文

共 28 条

[1] Effects of solvent and annealing on the improved performance of solar cells based on poly(3-hexylthiophene): Fullerene [J].

Al-Ibrahim, M ;

Ambacher, O ;

Sensfuss, S ;

Gobsch, G .

APPLIED PHYSICS LETTERS, 2005, 86 (20) :1-3

[2] Organic photovoltaics: technology and market [J].

Brabec, CJ .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2004, 83 (2-3) :273-292

[3] Influence of nanomorphology on the photovoltaic action of polymer-fullerene composites [J].

Chirvase, D ;

Parisi, J ;

Hummelen, JC ;

Dyakonov, V .

NANOTECHNOLOGY, 2004, 15 (09) :1317-1323

[4] Controlled living ring-opening-metathesis polymerization by a fast-initiating ruthenium catalyst [J].

Choi, TL ;

Grubbs, RH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (15) :1743-1746

[5] Supramolecular self-assembly and opto-electronic properties of semiconducting block copolymers [J].

de Boer, B ;

Stalmach, U ;

van Hutten, PF ;

Melzer, C ;

Krasnikov, VV ;

Hadziioannou, G .

POLYMER, 2001, 42 (21) :9097-9109

[6] Mechanisms controlling the efficiency of polymer solar cells [J].

Dyakonov, V .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2004, 79 (01) :21-25

[7] Correlation between structural and optical properties of composite polymer/fullerene films for organic solar cells [J].

Erb, T ;

Zhokhavets, U ;

Gobsch, G ;

Raleva, S ;

Stühn, B ;

Schilinsky, P ;

Waldauf, C ;

Brabec, CJ .

ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (07) :1193-1196

[8] FRACTAL AND COMPACT GROWTH MORPHOLOGIES IN-PHASE TRANSITIONS WITH DIFFUSION TRANSPORT [J].

IHLE, T ;

MULLERKRUMBHAAR, H .

PHYSICAL REVIEW E, 1994, 49 (04) :2972-2991

[9] Composition and annealing effects in polythiophene/fullerene solar cells [J].

Kim, Y ;

Choulis, SA ;

Nelson, J ;

Bradley, DDC ;

Cook, S ;

Durrant, JR .

JOURNAL OF MATERIALS SCIENCE, 2005, 40 (06) :1371-1376

[10] Device annealing effect in organic solar cells with blends of regioregular poly(3-hexylthiophene) and soluble fullerene [J].

Kim, Y ;

Choulis, SA ;

Nelson, J ;

Bradley, DDC ;

Cook, S ;

Durrant, JR .

APPLIED PHYSICS LETTERS, 2005, 86 (06) :1-3