Direct measure of the hydration number of aqueous methane

被引：70

作者：

Dec, SF ^{[1
]}

Bowler, KE ^{[1
]}

Stadterman, LL ^{[1
]}

Koh, CA ^{[1
]}

Sloan, ED ^{[1
]}

机构：

[1] Colorado Sch Mines, Ctr Res Hydrates, Dept Chem Engn, Golden, CO 80401 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 02期

关键词：

D O I：

10.1021/ja055283f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hydration number of 20 has been measured for aqueous CH4 in the temperature range 273-298 K on the basis of the simultaneous observation of the 13C isotropic resonance lines of CH4 in both aqueous solution and the dodecahedral cage of CH4 structure I hydrate. Additional experimental evidence and analysis reported in this paper suggest that the dominant aqueous hydration number of methane is 20. Copyright © 2006 American Chemical Society.

引用

页码：414 / 415

页数：2

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