Compatibilization of high-impact polystyrene/polypropylene blends

被引:82
作者
Horak, Z [1 ]
Fort, V [1 ]
Hlavata, D [1 ]
Lednicky, F [1 ]
Vecerka, F [1 ]
机构
[1] KAUCUK CO,RUBBER RES INST,CR-27852 KRALUPY,CZECH REPUBLIC
关键词
polymer blends; morphology; compatibilization;
D O I
10.1016/0032-3861(96)81600-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Effects of three different linear styrene-butadiene block copolymers on morphology and selected mechanical properties of high-impact polystyrene/polypropylene blends were investigated. Scanning and transmission electron microscopy and small-angle X-ray scattering were used for the determination of the blend morphology. Impact strength, elongation at break and flexural modulus were measured for further evaluation of the compatibilizer efficiency. A similar effect on the particle dispersion was found for all three copolymers but both the styrene-terminated multiblocks influence formation of interfacial layer and consequently the related mechanical properties in a much more pronounced way than the diblock. Small-angle X-ray scattering was found to be the appropriate technique for the determination of triblock concentration necessary for covering a given interfacial area (critical concentration).
引用
收藏
页码:65 / 73
页数:9
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