Positive temperature coefficient characteristics of poly(3-alkylthiophene)s

被引：11

作者：

Yamauchi, T

Najib, HM

Liu, YW

Shimomura, M

Miyauchi, S

机构：

来源：

SYNTHETIC METALS | 1997年 / 84卷 / 1-3期

关键词：

poly(3-alkylthiophene); chemically oxidative polymerization; electrochemical polymerization electrical properties; positive temperature coefficient characteristic;

D O I：

10.1016/S0379-6779(97)80866-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Poly(3-alkylthiophene)(P3AT) films were prepared by both electrochemical and chemically oxidative polymerization methods, and their positive temperature coefficient(PTC) characteristics were investigated in the range from 0 to 200 degrees C. The change in the amount of tetrafluoroborate ion(BF4-) or iron(III) perchlorate(FeCl3) which were doped into P3AT film was also estimated by infrared(IR) and ultraviolet(UV) spectrophotometry. It was found that the P3AT films chemically polymerized at a low temperature had PTC characteristics, which was not affected by the dedoping involved in thermal treatment.

引用

页码：581 / 582

页数：2