NMR observation of trialkylphosphite-palladium(II) and ruthenium(II) complexes in supercritical carbon dioxide

被引：23

作者：

Kayaki, Y

Suzuki, T

Noguchi, Y

Sakurai, S

Imanari, M

Ikariya, T

机构：

[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan

[2] CREST, JST, Meguro Ku, Tokyo 1528552, Japan

[3] JEOL Ltd, Tokyo 1968558, Japan

来源：

CHEMISTRY LETTERS | 2002年 / 04期

关键词：

D O I：

10.1246/cl.2002.424

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A supercritical fluid nuclear magnetic resonance (scNMR) spectroscopic method has been de eloped using a commercially available NMR spectrometer equipped with a high-pressure zirconia cell, revealing that trialkylphosphite ligands are highly effective for increasing the Solubility of dichloropalladium(II) and dichlororuthenium(II) Complexes in supercritical carbon dioxide (scCO(2)).

引用

页码：424 / 425

页数：2

共 19 条

[1]

AIZAWA T, 1998, REV HIGH PRESSURE SC, V7, P1426

[2]

[Anonymous], 1999, CHEM SYNTHESIS USING

[3] A new high pressure sapphire nuclear magnetic resonance cell [J].