Vibrational spectra and structure of tris(8-hydroxyquinoline)aluminum(III)

被引：73

作者：

Halls, MD

Aroca, R ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Mat & Surface Sci Grp, Windsor, ON N9B 3P4, Canada

[2] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

CANADIAN JOURNAL OF CHEMISTRY | 1998年 / 76卷 / 11期

关键词：

tris(8-hydroxyquinoline)aluminum; Alq(3); ab initio; assignments; infrared; Raman; thin films;

D O I：

10.1139/cjc-76-11-1730

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The vibrational spectra of one of the most commonly used light-emitting materials for organic electroluminescence (EL) devices, tris(8-hydroxyquinoline)aluminum (Alq(3),), is presented. The geometry and normal modes of fac-Alq(3) isomer in the ground state have been computed for the first time using ab initio methods (HF/6-31G*) to aid in discussion of normal-mode assignment. Normal inelastic scattering excited at 633 nm and low-temperature FT-Raman in addition to the infrared spectra of this material are reported. The vibrational characterization of thin solid films of the material was attempted using transmission and reflection-absorption FT-IR spectroscopy (RAIRS) on smooth silver films.

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页码：1730 / 1736

页数：7

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