A metal-organic framework with a hierarchical system of pores and tetrahedral building blocks

被引：198

作者：

Sudik, AC

Côté, AP

Wong-Foy, AG

O'Keeffe, M

Yaghi, OM ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

[2] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA

[3] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 16期

关键词：

iron; metal-organic frameworks; microporous materials; nanostructures; sorption;

D O I：

10.1002/anie.200600175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The whole is greater than the sum of its parts: Linking the porous tetrahedra of IRMOP-51 (brown) by connecting their iron-trimer vertices (red) with bipyridine linkers leads to the new metal-organic framework MOF-500, which contains additional smaller (blue) and larger (green and yellow spheres) tetrahedral pores. The sorption capacity of MOF-500 is four times greater than that of the molecular compound IRMOP-51. (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2528 / 2533

页数：6

共 36 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].