Synthesis and characterization of model fluoroacylated poly(ethylene oxide)

被引：26

作者：

Hartmann, P ^{[1
]}

Collet, A ^{[1
]}

Viguier, M ^{[1
]}

机构：

[1] Univ Montpellier 2, Lab Org Mol Evolu & Mat Fluores, UPRESA CNRS 5073, F-34095 Montpellier 05, France

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1999年 / 95卷 / 1-2期

关键词：

end-capped poly(ethylene oxide); fluoroacylated poly(ethylene oxide); fluoroalkyl telechelic polymer; amphiphilic polymer; hydroxy group titration;

D O I：

10.1016/S0022-1139(99)00017-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The modification of hydroxytelechelic poly(ethylene oxide)s (PEO) of molecular weights 10.000, 20.000 by a fluorinated acid leading to fluoroacylated poly(ethylene oxide)s (FA-PEO) is described. The one pot process involving the in situ generation of a fluorinated anhydride by reaction with N,N-dicyclohexylcarbodiimide (DCC) leads to complete modification of hydroxy end-groups. The reaction is catalyzed by dimethylaminopyridine (DMAP). A method, based on F-19-NMR spectroscopy, has been developed for the detection and titration of residual PEO hydroxy end-groups. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：145 / 151

页数：7

共 26 条

[1] A comparison between hydrophobically end-gapped poly(ethylene oxide) with ether and urethane bonds [J].