Mixed oxides with rutile type structure active in ammoxidation to acrylonitrile

被引：1

作者：

Albonetti, S ^{[1
]}

Cavani, F ^{[1
]}

Masetti, S ^{[1
]}

Trifiro, F ^{[1
]}

机构：

[1] Univ Bologna, Dept Ind Chem & Mat, I-40136 Bologna, Italy

来源：

SCIENCE AND TECHNOLOGY IN CATALYSIS 1998 | 1999年 / 121卷

关键词：

D O I：

10.1016/S0167-2991(99)80048-2

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The reactivities of the V/Sb/O catalytic system, characterized by the rutile type structure SbVO(4), and of iso-structural Sn/Sb/O, Fe/Sb/O and Ti/Sb/O samples were tested with respect to propane and propylene ammoxidation, in order to understand the particular characteristics of each single system. Owing to the activation property of vanadium, three ternary samples (Sn/V/Sb/O, Fe/V/Sb/O and Ti/V/Sb/O) were prepared and characterized with respect to propane ammoxidation, in order to mix the properties of each binary system with V/Sb/O and to synthetize a new catalyst active and selective in the direct functionalization of the paraffin.

引用

页码：79 / 84

页数：6

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