Preparation of LiMO2 (M = Co, Ni) cathode materials for intermediate temperature fuel cells by sol-gel processes

被引：35

作者：

Tao, SW ^{[1
]}

Wu, QY ^{[1
]}

Zhan, ZL ^{[1
]}

Meng, GY ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Anhua 230026, Peoples R China

来源：

SOLID STATE IONICS | 1999年 / 124卷 / 1-2期

关键词：

lithium cobalt oxide; lithium nickel oxide; sol-gel process; conductivity; fuel cell;

D O I：

10.1016/S0167-2738(99)00137-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

LiMO2 (M = Co, Ni) was prepared by complexing sol-gel processes. The phase and thermal stability were characterized by XRD and TG analyses. LiCoO2 and LiNiO2 phases are formed around 400 degrees C and 700 degrees C respectively in our synthesis process. LiNiO2 exhibit higher electrical conductivity and better H-2/O-2 fuel cell performance than LiCoO2 when used as cathode materials. But its thermal stability is relatively poorer than the later at intermediate temperature. (C) 1999 Elsevier Science BN. All rights reserved.

引用

页码：53 / 59

页数：7

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