A photo-hydrogen-evolving molecular device driving visible-light-induced EDTA-reduction of water into molecular hydrogen

被引：361

作者：

Ozawa, H

Haga, MA

Sakai, K ^{[1
]}

机构：

[1] Kyushu Univ, Fac Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan

[2] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1128551, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 15期

关键词：

D O I：

10.1021/ja058087h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A photo-hydrogen-evolving molecular device made up of a tris(2,2′-bipyridine)ruthenium(II) derivative and a dichloro(2,2′-bipyridine)platinum(II) derivative has been found to serve as the first effective model of a "molecular device" which evolves molecular hydrogen from water in the presence of a sacrificial electron donor (EDTA), under the visible-light illumination. Copyright © 2006 American Chemical Society.

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页码：4926 / 4927

页数：2

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