Homopolymers of 5-chloro-8-quinolinyl acrylate and 5-chloro-8-quinolinyl methacrylate and their copolymers with acrylic and methacrylic acid

被引：30

作者：

Bankova, M ^{[1
]}

Petrova, T ^{[1
]}

Manolova, N ^{[1
]}

Rashkov, I ^{[1
]}

机构：

[1] BULGARIAN ACAD SCI,INST POLYMERS,BU-1113 SOFIA,BULGARIA

来源：

EUROPEAN POLYMER JOURNAL | 1996年 / 32卷 / 05期

关键词：

D O I：

10.1016/0014-3057(95)00167-0

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Optimal conditions for the preparation of 5-chloro-8-quinolinyl acrylate (AQ) and 5-chloro-8-quinolinyl methacrylate (MQ) were found. Homopolymers were obtained by radical polymerization of AQ and MQ. Copolymers were obtained by copolymerization of AQ with acrylic acid (AA) and MQ with methacrylic acid (MA). The obtained monomers and polymers were characterized by spectroscopic methods (i.r., H-1 and C-13-NMR), gel-permeation chromatography (GPC) and differential scanning calorimetry (DSC). It was shown that the water-soluble copolymers of AA and AQ (AQ content 5 or 14 mol%) form interpolymer complexes with poly(N-vinyl-2-pyrrolidone).

引用

页码：569 / 578

页数：10

共 22 条

[1]

ALBERT A, 1971, SELECTIVE TOXICITY

[2] POLY(E-CAPROLACTONE)S WITH 5-NITRO AND 5-CHLORO-8-QUINOLINOXYL END-GROUPS [J].

BANKOVA, M ;

MANOLOVA, N ;

RASHKOV, I .

EUROPEAN POLYMER JOURNAL, 1994, 30 (10) :1179-1185

[3] 5-chloro-8-quinolinyl acrylate and N-vinyl-2-pyrrolidone copolymers: Synthesis, characterization and complexes with poly(methacrylic acid) [J].

Bankova, M ;

Petrova, T ;

Manolova, N ;

Rashkov, I .

EUROPEAN POLYMER JOURNAL, 1996, 32 (03) :325-330

[4] A NEW TYPE OF 8-QUINOLINOL AMEBACIDAL AGENT [J].

BURCKHALTER, JH ;

EDGERTON, WH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (10) :4837-4839

[5]

COLEMAN MM, 1987, POLYM PREPR, V28, P131

[6] PROTON MAGNETIC-RESONANCE STUDIES OF 8-HYDROXYQUINOLINE DERIVATIVES [J].

CORSINI, A ;

LOUCH, WJ ;

THOMPSON, M .

TALANTA, 1974, 21 (03) :252-255

[7]

DEGEISO RC, 1965, J APPL POLYM SCI, V2, P411

[8]

EMDEN HH, 1975, Patent No. 559182

[9] COMPLEXATION OF ACRYLIC-ACID COPOLYMERS WITH POLYBASES - IMPORTANCE OF COOPERATIVE EFFECTS [J].

ILIOPOULOS, I ;

AUDEBERT, R .

MACROMOLECULES, 1991, 24 (09) :2566-2575

[10]

ILIOPOULOS I, 1985, POLYM BULL, V13, P171

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