Raman and FTIR spectroscopic characterization of electrochemically synthesized poly(triphenylamine), PTPA

被引：52

作者：

Kvarnström, C ^{[1
]}

Petr, A

Damlin, P

Lindfors, T

Ivaska, A

Dunsch, L

机构：

[1] Abo Akad Univ, Analyt Chem Lab, Proc Chem Grp, SF-20500 Turku, Finland

[2] Inst Solid State Mat Res, Grp Electrochem & Conducting Polymers, D-01107 Dresden, Germany

来源：

JOURNAL OF SOLID STATE ELECTROCHEMISTRY | 2002年 / 6卷 / 08期

关键词：

poly(triphenylamine); FTIR external reflection spectroscopy; Raman spectroscopy;

D O I：

10.1007/s10008-002-0275-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Triphenylamine was electrochemically polymerized in a mixture of toluene and acetonitrile with different electrolyte salts. The poly(triphenylamine) (PTPA) films are insoluble in polar solvents and show high stability and no degradation or loss in electrochemical properties when stored in a laboratory atmosphere. The PTPA films were characterized in situ by FTIR external reflection spectroscopy and by Raman spectroscopy.

引用

页码：505 / 512

页数：8

共 34 条

[1] POLYANILINES AND SUBSTITUTED POLYANILINES - A COMPARATIVE-STUDY OF THE RAMAN-SPECTRA OF LEUCOEMERALDINE, EMERALDINE AND PERNIGRANILINE [J].

BERRADA, K ;

QUILLARD, S ;

LOUARN, G ;

LEFRANT, S .

SYNTHETIC METALS, 1995, 69 (1-3) :201-204

[2] Organic mixed valence systems .2. Two-centers and three-centers compounds with meta connections around a central phenylene ring [J].

Bonvoisin, J ;

Launay, JP ;

Verbouwe, W ;

VanderAuweraer, M ;

DeSchryver, FC .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (42) :17079-17082

[3] Vibrational analysis of polyaniline: A model compound approach [J].

Boyer, MI ;

Quillard, S ;

Rebourt, E ;

Louarn, G ;

Buisson, JP ;

Monkman, A ;

Lefrant, S .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (38) :7382-7392

[4] EQCM studies of polypyrrole films. 1. Exposure to aqueous sodium tosylate solutions under thermodynamically permselective conditions [J].

Bruckenstein, S ;

Brzezinska, K ;

Hillman, AR .

ELECTROCHIMICA ACTA, 2000, 45 (22-23) :3801-3811

[5] Electrochemical quartz crystal microbalance and spectroelectrochemical studies of the influence of cations on the formation and electroactivity of poly(N-vinylcarbazole) films in acetonitrile solutions [J].

Carlier, V ;

Skompska, M ;

Buess-Herman, C .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 456 (1-2) :139-152

[6] A SIMPLE INTERPRETATION OF THE VIBRATIONAL-SPECTRA OF UNDOPED, DOPED AND PHOTOEXCITED POLYACETYLENE - AMPLITUDE MODE THEORY IN THE GF FORMALISM [J].

CASTIGLIONI, C ;

NAVARRETE, JTL ;

ZERBI, G ;

GUSSONI, M .

SOLID STATE COMMUNICATIONS, 1988, 65 (07) :625-630

[7] Vibrational study of the base form of polyaniline: effect of the 3D character [J].

Cochet, M ;

Quillard, S ;

Buisson, JP ;

Lefrant, S ;

Louarn, G .

SYNTHETIC METALS, 1999, 101 (1-3) :793-794

[8]

DAMLIN P, 2002, IN PRESS J SOLID STA

[9]

Del Zoppo M., 1998, HDB CONDUCTING POLYM, P765

[10] AMPLITUDE AND PHASE MODES IN TRANSPOLYACETYLENE - RESONANT RAMAN-SCATTERING AND INDUCED INFRARED ACTIVITY [J].

EHRENFREUND, E ;

VARDENY, Z ;

BRAFMAN, O ;

HOROVITZ, B .

PHYSICAL REVIEW B, 1987, 36 (03) :1535-1553

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