Cobalt-carbene complex with single-bond character: Intermediate for the cobalt complex-catalyzed cyclopropanation

被引：73

作者：

Ikeno, T ^{[1
]}

Iwakura, I ^{[1
]}

Yamada, T ^{[1
]}

机构：

[1] Keio Univ, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 51期

关键词：

D O I：

10.1021/ja027713x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is generally considered that metal-carbene carbon bonds in carbene complexes for cyclopropanation should be double-bonded; however, the theoretical and FT-IR analyses revealed that the cobalt-carbene carbon bond of the 3-oxobutylideneaminato or the salen-cobalt-carbene complexes was characterized as a single bond. Copyright © 2002 American Chemical Society.

引用

页码：15152 / 15153

页数：2

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