Complexation of 4,4′-dipyridyl derivatives changed the orientations of metalloporphyrins linked to the cyclic peptide gramicidin S

被引:4
作者
Arai, T [1 ]
Araki, K
Fukuma, K
Nakashima, T
Kato, T
Nishino, N
机构
[1] Kyushu Univ, Inst Fundamental Res Organ Chem, Fukuoka 8128581, Japan
[2] Kyushu Inst Technol, Fac Engn, Kitakyushu, Fukuoka 8048550, Japan
[3] Kyushu Inst Technol, Grad Sch Life Sci & Syst Engn, Kitakyushu, Fukuoka 8080196, Japan
关键词
D O I
10.1246/cl.2002.1110
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pairs of Zn and Co(III) porphyrins linked to the natural cyclic beta-sheet peptide, Gramicidin S, formed stable host-guest complexes with the 4,4'-dipyridyl derivatives in dichloromethane, in which the Cotton effects reflected the orientational changes of the metalloporphyrins upon the complexations.
引用
收藏
页码:1110 / 1111
页数:2
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